Francesca Rosi, Laura Cartechini, Diego Sali,  and Costanza Miliani

Pages: 121–150
Abstract: The relevance of FT-IR spectroscopy in heritage science has experienced a constant grow in the last two decades owing to analytical peculiarities that make it an extremely useful tool to answer the questions posed by the study and conservation of art-historical and archaeological materials. High versatility, sensitivity and molecular specificity are, in fact, all requirements that FT-IR spectroscopy fulfils allowing for the investigation of the chemical properties of heritage materials spanning from the micro- to the macro-scale and offering a variety of approaches to minimize sample manipulation and maximize extracted information. Molecular identification and localisation at high lateral resolution of organic and inorganic components in micro-samples was, over recently, the mostly exploited use of FT-IR in heritage science; however, benefiting from technological progress and advances in optical materials and components achieved in the last decade, it now stands out also for noninvasive surface analysis of artworks by fully portable instrumentation.